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AP Chemistry
  • Pages
    • Class
      • Laboratory report rubric
      • Notes
        • 1. Chemical foundations
        • 2. Atoms, molecules, and ions
        • 3. Stoichiometry
        • 4. Types of chemical reactions and solution stoichiometry
        • 5. Gases
        • 6. Thermochemistry
        • 7. Atomic structure and periodicity
        • 8. Bonding: general concepts
        • 9. Covalent bonding: orbitals
        • 10. Liquids and solids
        • 11. Properties of solutions
        • 12. Chemical kinetics
        • 13. Chemical equilibrium
        • 14. Acids and bases
        • 15. Acid-base equilibria
        • 16. Solubility and complex ion equilibria
        • 17. Spontaneity, entropy, free energy
        • 18. Electrochemistry
      • Drug unit
        • Basics
        • Analgesics
        • Antacids
        • Anesthetics
        • Depressants
        • Stimulants
        • Antibiotics
        • Antiviral drugs
        • Mind-altering drugs
    • Textbook (incomplete)
      • 1. Chemical foundations
      • 2. Atoms, molecules, and ions
      • 3. Stoichiometry
      • 4. Types of chemical reactions and solution stoichiometry
      • 5. Gases
      • 6. Thermochemistry
      • 7. Atomic structure and periodicity
      • 8. Bonding: general concepts
    • CED
      • 1. Atomic structure and properties
      • 2. Compound structure and properties
      • 3. Properties of substances and mixtures
      • 4. Chemical reactions
      • 5. Kinetics
      • 6. Thermochemistry
      • 7. Equilibrium
      • 8. Acids and bases
      • 9. Thermodynamics and electrochemistry

14. Acids and bases

Acids and bases

acid
base
sour
bitter
H
OH
donates H⁺ (proton)
accepts H⁺ (proton)
There are no rows in this table

K_a and K_w

K for acids
K_a: tells you the strength of the acid
strong: dissociates completely (~100%)
K_a is infinite (division by ~0)
weak: dissociates partially
K_a is small
amphoteric: can be an acid or a base (e.g. water)
pure water: when [H₃O⁺] = [OH⁻]
find concentration of pure water
autoionization: when one water reacts with another water
change value of K by changing temperature
K_w differs at different temperatures

pH and pOH

for an acid
0 to 14
7: pure
< 7: acid
> 7: base
for an acid
0 to 14
7: pure
< 7: base
> 7: acid
opposite for a base
pH + pOH = 14
example: what is the pH of an acid with concentration 0.001 M?

Titrations

titration: experiment to determine the concentration of an unknown acid or base
image.png
known acid/base goes into the burette
unknown acid/base goes into the flask
stopcock
perpendicular: closed
parallel: open
indicator
changes color at specific pH
located in flask with unknown
image.png
pH based on the amount of known substance
equivalence point: where molarities of acids and bases are equal
a: acid
b: base
acid
base
equivalence point
strong
strong
7
weak
strong
> 7
strong
weak
< 7
weak
weak
depends
There are no rows in this table

K_b

K_b: tells you the strength of the base
strong: dissociates completely (~100%)
K_a is infinite (division by ~0)
weak: dissociates partially
K_a is small
half-equivalence point (halfway to the equivalence point):

pH for acids and bases

strong
acid:
base:
weak
get the concentration of [H₃O⁺] or [OH⁻] from K_a or K_b
find pH using formula
example (acid):

HF
H⁺
F⁻
initial
1.00 M
0.00 M
0.00 M
change
- x
+ x
+ x
equilibrium
1.00 - x
0 + x
0 + x
There are no rows in this table
find concentration of H⁺
x will be very small so due to significant figures you can use x^2/1 instead of x^2/(1-x)
simpler way
percent dissociation:
example: add NaF to
; what happens to pH
add to the right → shifts left
pH goes up because fewer H⁺ so more basic

Polyprotic acids

polyprotic acid: acid with more than one H in the formula
many + proton + acid
example: H₃PO₄
as you go through the steps it becomes harder to remove H
strong acids: HCl, HBr, HI, H₂SO₄ (polyprotic), HClO₄, HNO₃
H₂SO₄
K_a_1: infinite
K_a_2: weak

Structures of acids and bases

an acid is stronger if:
it has more oxygen
it has a higher electronegativity
pulls electrons away from the H which makes the H fall off
base: opposite of acids (stronger if fewer oxygens, lower electronegativity)
because
conjugate acid/base

 
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